There are so many ways to top up your SIM card with Vodafone:
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Scratch cards are available in any Vodafone Store and in any tobacconist. Once buyed, all you need to do to top up is: carefully scratch off the silver panel of the Top Up scratch card, call the free number 42010 and give the number of the scratch card when prompted by the automatic system. After few minutes you will get an SMS to confirm you the top up.
Otherwise you can buy a scratch card in any Totobit or Lottomatica store.
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Top up electronically at one of the many ATM machines.
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If you have a credit card, register and top-up online at www.vodafone.it.
Among the services available on the www.vodafone.it, you can choose Telericarica Più, the easy and safe free service that allows you to top up your mobile phone wherever you are, 24 hours a day, 7 days a week.